01 - Preheat oven to 350°F. Grease and line two 8-inch round cake pans with parchment paper.
02 - Whisk flour, baking powder, and salt in a medium bowl.
03 - Beat eggs and sugar with electric mixer on high speed until pale and tripled in volume, about 5 to 7 minutes.
04 - Gently fold dry ingredients, lemon zest, and vanilla into egg mixture.
05 - Add melted butter and milk, mixing until just combined. Avoid overmixing.
06 - Divide batter evenly between prepared pans. Bake for 25 to 30 minutes or until toothpick comes out clean.
07 - Cool cakes in pans for 10 minutes, then turn out onto wire racks to cool completely.
08 - Heat water and sugar over medium heat until dissolved. Remove from heat, cool slightly, then stir in limoncello.
09 - Whip heavy cream to soft peaks. In separate bowl, whisk mascarpone, powdered sugar, lemon zest, and vanilla until smooth. Fold whipped cream into mascarpone mixture.
10 - Slice cakes horizontally for four thin layers. Place first layer on serving plate. Brush with limoncello syrup and spread mascarpone filling. Repeat with remaining layers, frosting top and sides.
11 - Garnish with lemon slices, zest, white chocolate curls, or edible flowers as desired.
12 - Refrigerate for at least 1 hour before serving for optimal flavor and texture.